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Technical document

SA styryl acrylonitrile copolymer injection molding

2024-12-18 16:13:59 SA

1. Properties of SA

Chemical and Physical Traits

SA, a hard and transparent material, resists internal stress cracking well. It has high transparency, with a softening temperature and impact strength higher than PS. Styrene in SA makes it hard, transparent, and easy to process, while acrylonitrile provides chemical and thermal stability. SA can bear loads, resist chemical reactions, thermal deformation, and maintain geometric stability. Adding glass fiber boosts its strength, thermal deformation resistance, and reduces thermal expansion. SA's Vicat softening temp is around 110 °C, deflection temp under load about 100 °C, and shrinkage rate 0.3 - 0.7%.

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2. Process Features of SA

SA is processed at 200 - 250 °C. Being hygroscopic, it must be dried over an hour before use. Its fluidity is a bit worse than PS, so injection pressure (350 - 1300 bar) should be slightly higher, and high - speed injection is advised. The mold temp is set at 45 - 75 °C. If not stored right, SA absorbs moisture. Recommended drying is at 80 °C for 2 - 4 hours, with a melting temp of 200 - 270 °C. For thick - walled items, use a lower melting temp. For reinforced SA, mold temp should not exceed 60 °C. A well - designed cooling system is crucial as mold temp impacts product appearance, shrinkage, and bending. All regular gates work, but the size must be proper to avoid stripes, burns, and voids.

3. Typical Applications

  • Electrical (sockets, housings)

  • Daily goods (kitchenware, fridge parts, TV bases)

  • Automotive (headlight boxes, mirrors, dashboards)

  • Household (tableware, food knives)

  • Cosmetic packaging (safety glass, water filter housings)

  • Medical (syringes, dialysis gear)

  • Packaging (cosmetic boxes, bottle caps)

  • Special items (lighter housings, fishing gear, toothbrush handles)

4. Injection Molding Process

4.1 Raw Material Prep

  • Drying: SA, being hygroscopic, needs drying before molding. Moisture causes surface defects. Dry at 70 - 80 °C for 2 - 4 hours to reduce water content below 0.1%.

  • Coloring: Add masterbatches (1% - 5% depending on color depth) for specific colors and mix well.

  • injection mould

4.2 Injection Molding Machine

  • Selection: Pick a screw - type machine with an L/D ratio of 18 - 22. Clamping force is 1 - 3 tons per cm2 of product projected area.

  • Temp Control: Barrel temp: 180 - 200 °C (hopper end), 200 - 220 °C (middle), 220 - 240 °C (nozzle end); nozzle at 220 - 230 °C. Mold temp is 60 - 80 °C.

4.3 Pressure & Speed

Injection pressure is 70 - 120 MPa. Injection speed, 30 - 80 mm/s, is adjusted by product thickness: higher for thin - walled, lower for thick - walled.

4.4 Mold Closing

Close the moving and fixed molds at a moderate speed to prevent overflow and damage.

4.5 Injection

Inject plasticized SA into the mold, watching for pressure and speed changes.

4.6 Holding Pressure

Apply 50% - 70% of injection pressure as holding pressure for 3 - 5 seconds per mm of product thickness.

4.7 Cooling

Cool the product in the mold for 10 - 30 seconds, depending on thickness.

4.8 Mold Opening & Demolding

Open the mold and eject the product. Use release agents and choose the right demolding method.

4.9 Product Post - treatment

  • Trim flash with tools or machines.

  • Do surface treatments like polishing, painting, or electroplating.

  • Check product quality by inspecting appearance, dimensions, and performance.

injection mould


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